TFSI产业化 之 LiTFSI及TFSI-ILs性质、应用（汇总中...）

默尼（Monils） - 立足TFSI离子液体产业化，致力于其产能提升、成本降低、应用拓展，欢迎大家参与或提供更多相关信息（QQ: 3078182654  E-mail: heqing@ilschem.cn）。

LiTFSI     [量产，目前100吨/年，计划1~2年后500吨/年]        

Li-TFSI

双三氟甲磺酰亚胺锂  99.9% CAS：90076-65-6 粉体、水溶、易吸潮

TFSI-ILs（TFSI离子液体）[以下几款承上量产]

EMI-TFSI	1-乙基-3-甲基咪唑双三氟甲磺酰亚胺盐 99% CAS：174899-82-2 无色透明液体、疏水
BMI-TFSI	1-丁基-3-甲基咪唑双三氟甲磺酰亚胺盐 99% CAS：174899-83-3 无色透明液体、疏水
TBMA-TFSI	三丁基甲基铵双三氟甲磺酰亚胺盐 98%（近99%） CAS：405514-94-5 无色透明液体（熔点：28℃） 疏水
TBTA-TFSI	三丁基十四烷基膦双三氟甲磺酰亚胺盐 98%（近99%） 无色透明液体 疏水

性质、应用（欢迎提供相关文献）

1. 抗静电（添加剂）

   高透光性，ppm级添加量即可显著降低表面电阻，显著提升亚克力、PU、PC等树酯或胶粘剂抗静电性能

   (1) Antistatic effects of ionic liquids for polyether-based polyurethanes, Electrochimica Acta, Volume 175, 1 September 2015, Pages 13-17 

   (2) Bis(trifluoromethanesulfonyl)imide‐Type Ionic Liquids as Excellent Antistatic Agents for Polyurethanes, Macromol. Mater. Eng., 2014, 299, 794-798

   (3) Fixation of ionic liquids into polyether-based polyurethane films to maintain long-term antistatic properties,  Polymer, Volume 55, Issue 10, 13 May 2014, Pages 2501-2504

   
   

2. 离子凝胶/膜

   离子凝胶，以离子液体为分散介质，保留离子液体固有属性之余，解决离子液体外溢问题，提高离子液体可塑性。

   (1) Versatile Supramolecular Gelators That Can Harden Water, Organic Solvents and Ionic Liquids,  dx.doi.org/10.1021/la301442f| Langmuir 2012, 28, 9259−9266
   

   2.1 电致变色

   (1) Flexible and Transparent Electrochromic Displays with Simultaneously Implementable Subpixelated Ion Gel‐Based Viologens by Multiple Patterning, Adv. Funct. Mater. 2019, 29, 1808911

   2.2 磁电调控

   (1) Low-Voltage Control of (Co/Pt)x Perpendicular Magnetic Anisotropy Heterostructure for Flexible Spintronics, ACS Nano 2018 12 (7), 7167-7173

   2.3 电解质

   (1) Ion Gels Prepared by in Situ Radical Polymerization of Vinyl Monomers in an Ionic Liquid and Their Characterization as Polymer Electrolytes, J. AM. CHEM. SOC. 9 VOL. 127, NO. 13, 2005 4977

   (2) Non-volatile, Li-doped ion gel electrolytes for flexible WO3-based electrochromic devices, Materials & Design, Volume 162, 15 January 2019, Pages 45-51

   2.4 自组装

   (1) Effects of Cooling Rates on Self-Assembling Structures of 12-Hydroxystearic Acid in an Ionic Liquid, Advances in Materials Science and Engineering, Volume 2017, Article ID 4762379, 8 pages

   2.5 导电膜

   (1) Effect of Confinement on Proton Transport Mechanisms in Block Copolymer/Ionic Liquid Membranes, Macromolecules 2012, 45, 3112−3120
   

   
   

3. 润滑（添加剂）

   (1) Dramatically improved friction reduction and wear resistance by in situ formed ionic liquids, Received 9th May 2012, Accepted 14th May 2012

   
   

4. 吸收（吸收剂）、萃取（萃取剂）

   4.1 药物残留富集

   (1) Developing microwave-assisted ionic liquid microextraction for the detection and tracking of hydrophobic pesticides in complex environmental matrices, RSC Adv., 2013, 3, 17113–17119

   4.2 离子捕集

   (1) Extraction of lithium from salt lake brine using room temperature ionic liquid in tributyl phosphate, Solvent Extraction Research and Development, Japan, Vol. 25, No. 2, 117-123 (2018)

   
   

5. 催化（催化剂）

   5.1 烷基化反应

   (1) Synthesis of efficient SBA-15 immobilized ionic liquid catalyst and its performance for Friedel–Crafts reaction, Catalysis Today, 276 (2016) 112–120

   
   

6. 场效应、半导体

   参考链接：http://itp.energy.hust.edu.cn/info/1029/1383.htm